School of Chemical Sciences   |   College of Liberal Arts & Sciences  |   College of Engineering

 

Richard D. Braatz

Richard D. Braatz

Contact Information:
e-mail:
phone: (217) 333-5073
fax: (217) 333-5052

293 RAL
MC-712, Box C-3
600 S. Mathews Ave.
Urbana, IL 61801

Millennium Chair
B.S., Oregon State University, 1988
M.S., California Institute of Technology, 1991
Ph.D., California Institute of Technology, 1993

Multiscale Systems and Control

New applications in materials, medicine, and computers are being discovered where the control of events at the molecular and nanoscopic scales is critical to product quality, although the primary manipulation of these events during processing occurs at macroscopic length scales. This drives our research program in the creation of methods for the simulation, design, and control of multiscale systems that have length scales ranging from the atomistic to the macroscopic.

Microelectronics/materials

Applications include the formation of transistor junctions in advanced CMOS devices (in collaboration with Prof. E. Seebauer), and the manufacture of copper interconnects in electronic devices (in collaboration with Prof. R. Alkire). For ultrashallow junctions, the results motivate the design of new rapid thermal annealing processes while providing specific recommendations for microelectronics tool manufacturers on how to optimize processes to produce shallower junctions of higher electrical activation. For copper interconnects, systems principles are used to gain fundamental insights into surface reaction mechanisms, and to design new molecular additives to increase the geometric uniformity of interconnects from the nanometer to wafer length scales.

Biomedical/pharmaceutical

Applications include the modeling and design of biodegradable polymeric drug delivery systems (in collaboration with Prof. D. Pack) and the formation of high quality protein or pharmaceutical crystals from solution. For drug delivery, our goal is to model the relationship between the polymer geometry, molecular weight distribution, and microstructure to the release of drugs or growth factors, and to use these models to optimally design drug delivery systems to achieve a desired temporal and spatial release. In our crystallization effort, we are developing an integrated approach to control crystal formation that includes (i) simulating the nucleation, growth, and aggregation of crystals including the effects of micro- and macromixing, (ii) utilizing video microscopy, laser backscattering, ATR-FTIR, and Raman spectroscopy for the in-situ measurement of the size, shape, and polymorphism of crystals during crystal formation, and (iii) designing algorithms to control the properties of the product crystals.
 

Selected Publications

Z. Zheng, R. Stephens, R. D. Braatz, R. C. Alkire, and L. R. Petzold, "A hybrid multiscale kinetic Monte Carlo method for simulation of copper electrodeposition," Journal of Computational Physics, 227, 5184-5199 (2008).

C. T. M. Kwok, K. Dev, E. G. Seebauer, and R. D. Braatz, "Maximum a posteriori estimation of activation energies that control silicon self-diffusion," Automatica, 44, 10 (2008).

N. Nair, W.J. Kim, R.D. Braatz and M.S. Strano, "Dynamics of surfactant-suspended single-walled carbon nanotubes in a centrifugal field," Langmuir, 24, 1790-1795 (2008)

J. G. VanAntwerp, A. P. Featherstone, R. D. Braatz, and B. A. Ogunnaike, "Cross-directional control of sheet and film processes," Automatica, 43, 191-211 (2007).

G. X. Zhou, M. Fujiwara, X. Y. Woo, E. Rusli, H.-H. Tung, C. Starbuck, O. Davidson, Z. H. Ge, and R. D. Braatz, "Direct design of pharmaceutical antisolvent crystallization through concentration control," Crystal Growth & Design, 6, 892-898 (2006).

E. G. Seebauer, K. Dev, M. Y. L. Jung, R. Vaidyanathan, C. T. M. Kwok, J. W. Ager, E. E. Haller, and R. D. Braatz, "Control of defect concentrations within a semiconductor through adsorption," Physical Review Letters, 97, 055503 (2006).

X. Y. Woo, R. B. H. Tan, P. S. Chow, and R. D. Braatz, "Simulation of mixing effects in antisolvent crystallization using a coupled CFD-PDF-PBE approach," Crystal Growth & Design, 6, 1291-1303 (2006).

N. Nair, M. L. Usrey, W. J. Kim, R. D. Braatz, and M. S. Strano, "Estimation of the (n,m) concentration distribution of single-walled carbon nanotubes from photoabsorption spectra," Analytical Chemistry, 78, 7689-7696 (2006).

E. J. Hukkanen, J. A. Wieland, A. Gewirth, D. E. Leckband and R. D. Braatz, "Multiple-bond kinetics from single-molecule pulling experiments: Evidence for multiple NCAM bonds," Biophysical Journal, 89, 3434-3445 (2005).